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Lifetimes of vibro-rotational levels for excited electronic states of the diatomic hydrogen isotopologues

机译:激发电子态的振动旋转水平的寿命   双原子氢同位素

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摘要

Current situation in studies of lifetimes of excited rovibronic levels forthe H2, D2, T2, HD, HT, and DT molecules is analyzed. All measured values ofthe lifetimes (792 data for 618 different vibro-rotational levels of 33electronic states), reported in 61 publications before November 2014, arecompiled and listed in the tabular format together with annotated bibliography.Experimental data are now available for the H2, HD and D2 molecules only. Thedata collected in the present work show fragmentariness of experimental data.For vast majority of the levels the lifetime value was reported in one paperonly, and has no independent experimental verification. Complete bibliographyof publications concerning semi-empirical determination and non-empiricalcalculations of the lifetimes is presented. Numerical results obtained by thesetwo approaches are listed in an explicit form only in the cases whenexperimental data are available. For more than half of the levels thedifferences between measured and calculated values are 3 times higher thanexperimental errors. This direct contradiction shows necessity of more preciseexperimental and non-empirical studies. For finite number of rovibronic levelsour analysis made it possible to propose certain set of recommended data.
机译:分析了H2,D2,T2,HD,HT和DT分子受激振子水平的寿命研究现状。 2014年11月之前在61个出版物中报告的所有寿命测量值(用于618种不同振动状态的332种电子状态的792个数据)均已汇总并以表格形式与带注释的书目一起列出.H2,HD的实验数据现已提供和D2分子。本文收集的数据表明实验数据是零碎的。对于大多数水平,寿命值仅在一篇论文中报告,并且没有独立的实验验证。介绍了有关寿命的半经验性确定和非经验性计算的出版物的完整书目。仅在有实验数据的情况下,以显式形式列出通过这两种方法获得的数值结果。对于一半以上的水平,测量值与计算值之间的差异是实验误差的3倍。这种直接矛盾表明有必要进行更精确的实验和非经验研究。对于有限数量的电子振动水平,我们的分析使得可以提出一组推荐数据。

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